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Sweet Memory: Oligosaccharide-based Nanostructured Thin Films as the Charge Storage

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Sweet Memory: Oligosaccharide-based  Nanostructured Thin Films as the Charge Storage

Glycopolymer or polysaccharide is the biomass production of cellulose or straw, making it an inexhaustible source of raw materials for environmentally friendly and biocompatible products. However, integrating bio-based materials into electronics with high-performance efficiency has become a significant challenge. Thus, Prof. Chen and Prof. Borsali started the cross-country collaboration to develop oligosaccharide-based nanostructured thin films as the charge storage layer for electrical memory devices, through their hydroxyl group composition and self-assembly nanostructures. The collaboration was well funded with two important projects granted by CNRS-MOST and ANR-MOST. This research project received the Franco-Taiwanese Scientific Grand Prize 2018, jointly awarded by the Académie des Sciences and the MOST.


When we talk about sugar, we are fascinated by nature’s ability to produce sweetness. What if this sweetness would preserve memory? The long-time research collaboration between Prof. Wen-Chang Chang from National Taiwan University, and Prof. Redouane Borsali from Grenoble Alpes University made “sweet memory” a reality.

Better than sweetness, the two prof. received the Franco-Taiwanese Scientific Grand Prize 2018, jointly awarded by the Académie des Sciences and the MOST in November 2018, for the research’s originality in demonstrating that sugar-based block copolyemers could be employed for green non-volatile electrical memory devices and have a high potential for commercial applications on smart cards and wearable electronics.

SweetMemory
 
Glycopolymer or polysaccharide is the biomass production of cellulose or straw, making it an inexhaustible source of raw materials for environmentally friendly and biocompatible products. However, integrating bio-based materials into electronics with high-performance efficiency has become a significant challenge. Thus, Prof. Chen and Prof. Borsali started the Taiwan-France collaboration to develop oligosaccharide-based nanostructured thin films as the charge storage layer for electrical memory devices, through their hydroxyl group composition and self-assembly nanostructures. The collaboration was well funded with two important projects granted by CNRS-MOST and ANR-MOST. 
 
SweetMemory
 
Prof. Chen and Prof. Borsali discovered the sugar-based block copolymer, maltoheptaose-block-polystyrene(MH-b-PS), and their supramolecules of with 1-aminopyrene (APy) could serve as gate electrets for achieving high-performance organic field effect transistor memory devices. The non-volatile flash memory behaviors using the MH-b-PS electret were manipulated by the morphological transfer from the random sphere, to vertical cylinders, and horizontal cylinders. The supramolecules MH(APy) electret further enhanced the hole-trapping capability with the excellent characteristics of a wide memory window, long retention time with a high ON/OFF-current ratio, and stable reversibility. Then, by using oligosaccharides, such as maltoheptaose, maltoheptaose dextran, and polysucrose as the gate dielectric, they provided an irreversible electron-trapping property and achieved high-performance non-volatile write-one-read-memory (WORM) OFET memory. The trapping mechanism was attributed to charged hydroxyl groups and the formation of strong hydrogen bonding, which stabilized trapped charges.
 
Sweet Memory_
 
More recently, the research further discovered that the memory-type behaviors of MH-b-PI block copolymers based devices, including WORM, Flash and DRAM, could be easily controlled by the self-assembly nanostructures (vertical cylinder, horizontal cylinder and order-packed sphere). The electrical properties of the fabricated intrinsically stretchable resistive memory devices were maintained over 500 cycles upon 40% strain. Furthermore, the research explored a novel approach to using microwave energy to manipulate the morphology of carbohydrate-based block copolymer thin films with 7nm resolution.
 
In 2018, this study discovered that the molecular architecture effects on the morphology and properties of stretchable block copolymers of linear-type, and star-shaped architectures composed of oligosaccharide and flexible poly(n-butyl acrylate) blocks, for the application of the stretchable green electronic devices. 
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